says physicist David Tyler at Access Research Network:
It is universally claimed that the early Earth had a reducing atmosphere. Models have been proposed for the gases to have accumulated after outgassing of volatiles from volcanism. This reducing atmosphere was originally thought to have been dominant throughout the Precambrian, but signs of oxygenation have pushed it back earlier than the earliest rocks that researchers have discovered. The earlier claims for a reducing atmosphere have other explanations, such as resulting from the action of hydrodynamic fluids. This has put severe constraints on theories of abiogenesis, because the proposed mechanisms typically presuppose a reducing atmosphere. By the earliest Archaean, the atmosphere was at least neutral – so abiogenesis is inferred to have occurred even earlier. But moving back earlier brings us to the Late Heavy Bombardment which is generally deemed to have obliterated all traces of any life that may have been present. So there is a little window in the Hadean that is deemed to have offered a reducing atmosphere free from the destructive bombardment.
The evidence for a Hadean reducing atmosphere has been entirely theoretical. It does not rest on empirical evidence because there has been so little to work with. However, a new study of zircon crystals has reported some fascinating results that allow speculation about the Hadean black box to be replaced by empirical evidence. Zircons have been identified that carry signatures identifying them with the Hadean – and zircons are remarkably stable once formed. Using zircons dated to almost 4.4 Ga, the researchers have analysed their redox state (a measure of the degree of oxygenation of the mineral). This gives a handle on the type of gases that would have been outgassed by the magmas, and so, according to these models of Earth history, the type of atmosphere that would have been formed.
It is important to realise what was predicted by prevailing theories: the redox state of the magmas with which the zircons were associated was expected to be strongly reducing. This prediction is a necessary part of the Earth having a reducing atmosphere in the Hadean. The research findings did not confirm the prediction.
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